论文成果
Convenient Synthesis of Benzothiazoles and Benzimidazoles through Bronsted Acid Catalyzed Cyclization of 2-Amino Thiophenols/Anilines with beta-Diketones
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- 论文类型：期刊论文
- 发表时间：2014-02-07
- 发表刊物：ORGANIC LETTERS
- 收录刊物：PubMed、SCIE、Scopus
- 文献类型：J
- 卷号：16
- 期号：3
- 页面范围：764-767
- ISSN号：1523-7060
- 摘要：Bronsted acid catalyzed cyclization reactions of 2-amino thiophenols/anilines with beta-diketones under oxidant-, metal-, and radiation-free conditions are described. Various 2-substituted benzothiazoles/benzimidazoles are obtained in satisfactory to excellent yields. Different groups such as methyl, chloro, nitro, and methoxy linked on benzene rings were tolerated under the optimized reaction conditions.
