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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
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NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes
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论文类型：期刊论文
发表时间：2014-01-01
发表刊物：CHEMICAL COMMUNICATIONS
收录刊物：SCIE、Scopus
卷号：50
期号：99
页面范围：15730-15732
ISSN号：1359-7345
摘要：We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regio-selectivity in terms of cosolvents and nucleophiles.