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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
办公地点：精细化工国家重点实验室E504
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Co-Catalyzed Radical Cycloaddition of [60]Fullerene with Active Dibromides: Selective Synthesis of Carbocycle-Fused Fullerene Monoadducts
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论文类型：期刊论文
发表时间：2013-08-02
发表刊物：ORGANIC LETTERS
收录刊物：Scopus、SCIE
卷号：15
期号：15
页面范围：4030-4033
ISSN号：1523-7060
摘要：An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.