包明

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教授

博士生导师

硕士生导师

性别:男

毕业院校:日本东北大学

学位:博士

所在单位:化工学院盘锦分院

办公地点:精细化工国家重点实验室E504

电子邮箱:mingbao@dlut.edu.cn

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Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd(Ph2PCH2CO2)(2) as a precatalyst

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论文类型:期刊论文

发表时间:2010-06-01

发表刊物:CHINESE CHEMICAL LETTERS

收录刊物:SCIE、ISTIC、CSCD

卷号:21

期号:6

页面范围:641-645

ISSN号:1001-8417

关键字:Suzuki reaction; Bromoallene; Palladium complex

摘要:Suzuki reaction of bromoallenes with arylboronic acids was successfully performed by using an air-stable hemilabile P-O coordinated cyclopalladated complex Pd(Ph2PCH2CO2)(2) as a precatalyst, and the corresponding coupling products were obtained in satisfactory to excellent yields. All products are unknown compounds which were characterized by H-1 NMR, C-13 NMR, IR, and HRMS. (C) 2010 Xiu Juan Feng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.