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Stereoselective Synthesis of Vinyl Iodides through Copper(I)-Catalyzed Finkelstein-Type Halide-Exchange Reaction

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Indexed by:期刊论文

Date of Publication:2017-06-01

Journal:SYNTHESIS-STUTTGART

Included Journals:Scopus、SCIE、EI

Volume:49

Issue:12

Page Number:2727-2732

ISSN No.:0039-7881

Key Words:stereoselective synthesis; vinyl iodides; vinyl bromides; copper catalyst; halide-exchange reaction

Abstract:An efficient method for the stereoselective synthesis of vinyl iodides is described. The reactions of vinyl bromides with potassium iodide proceed smoothly in the presence of a copper catalyst under mild reaction conditions to produce the corresponding vinyl iodides stereospecifically and in satisfactory to excellent yields.

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