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Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via eta(3)-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization

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Indexed by:期刊论文

Date of Publication:2011-10-07

Journal:ORGANIC LETTERS

Included Journals:PubMed、Scopus、SCIE

Volume:13

Issue:19

Page Number:5402-5405

ISSN No.:1523-7060

Abstract:Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or pare-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via eta(3)-benzylpalladium Intermediates.

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