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论文类型：期刊论文

发表时间：2017-04-01

发表刊物：CHINESE CHEMICAL LETTERS

收录刊物：SCIE、CSCD

卷号：28

期号：4

页面范围：900-904

ISSN号：1001-8417

关键字：5-Vinyl-2-norbornene; Diels-Alder reaction; Cyclopentadiene; 1,3-Butadiene; Supercritical carbon dioxide

摘要：An efficient method for the synthesis of 5-vinyl-2-norbornene from cyclopentadiene and 1,3-butadiene was developed. The Diels-Alder reaction of cyclopentadiene with 1,3-butadiene proceeded smoothly in supercritical carbon dioxide in the absence of any polymerization inhibitor to produce the corresponding 5-vinyl-2-norbornene in satisfactory yield with high selectivity. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.