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个人信息Personal Information
副教授
硕士生导师
性别：男
毕业院校：中科院山西煤化所
学位：博士
所在单位：化学学院
学科：物理化学
办公地点：化工综合楼C213
联系方式：tiandx@dlut.edu.cn；13940816371
电子邮箱：tiandx@dlut.edu.cn
Uniform PdH0.33 nanodendrites with a high oxygen reduction activity tuned by lattice H
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论文类型：期刊论文
发表时间：2019-05-01
发表刊物：ELECTROCHEMISTRY COMMUNICATIONS
收录刊物：SCIE、EI
卷号：102
页面范围：67-71
ISSN号：1388-2481
关键字：Palladium hydride; Nanodendrites; Oxygen reduction reaction; Oxygen adsorption energy
摘要：We report the synthesis of beta-palladium hydride nanodendrites (PdH0.33 NDs). The uniform PdH0.33 NDs are 36.3 +/- 5.0 nm in diameter and selectively expose (111) planes decorated with (221) and (331) high-indexed steps. The PdH0.33 NDs show a high mass activity of 0.719 A/mg(Pd) at 0.9 V (vs. reversible hydrogen electrode-RHE) toward alkaline oxygen reduction reaction (ORR), which is 3.7 and 6.3 times that of commercial Pt/C and house-made Pd/C, respectively. This study exemplifies the possibility of using special morphology and lattice H to modify the strain and electronic effect of metal for the optimization of functionalities.