Catalytically active single-atom niobium in graphitic layers
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论文类型：期刊论文
发表时间：2013-05-01
发表刊物：NATURE COMMUNICATIONS
收录刊物：SCIE、PubMed、Scopus
卷号：4
页面范围：1924
ISSN号：2041-1723
摘要：Carbides of groups IV through VI (Ti, V and Cr groups) have long been proposed as substitutes for noble metal-based electrocatalysts in polymer electrolyte fuel cells. However, their catalytic activity has been extremely limited because of the low density and stability of catalytically active sites. Here we report the excellent performance of a niobium-carbon structure for catalysing the cathodic oxygen reduction reaction. A large number of single niobium atoms and ultra small clusters trapped in graphitic layers are directly identified using state-of-the-art aberration-corrected scanning transmission electron microscopy. This structure not only enhances the overall conductivity for accelerating the exchange of ions and electrons, but it suppresses the chemical/thermal coarsening of the active particles. Experimental results coupled with theory calculations reveal that the single niobium atoms incorporated within the graphitic layers produce a redistribution of d-band electrons and become surprisingly active for O-2 adsorption and dissociation, and also exhibit high stability.
发表时间：2013-05-01