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Redox-induced Ru(bpy)(3)(2+) -methylviologen radical formation and its dimerization in cucurbit[8]uril

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2011-01-14

Journal: PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Included Journals: Scopus、SCIE、PubMed

Volume: 13

Issue: 2

Page Number: 570-575

ISSN: 1463-9076

Abstract: A redox-induced radical Ru(bpy)(3)(2+)-(CH2)(n)-MV+center dot (n = 4, 7) and its dimerization in cucurbit[8] uril (CB[8]) have been observed concomitantly in aqueous solution, which depends heavily on the length of the carbon chain linkage, in the case of n = 4, the characteristic pattern for the radical dimer is predominating, while that for the radical becomes dominated for n = 7.

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