郭慧敏

个人信息Personal Information

副教授

硕士生导师

性别:女

毕业院校:Regensburg大学

学位:博士

所在单位:化学学院

学科:分析化学

电子邮箱:guohm@dlut.edu.cn

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Accessing the long-lived near-IR-emissive triplet excited state in naphthalenediimide with light-harvesting diimine platinum(II) bisacetylide complex and its application for upconversion

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论文类型:期刊论文

发表时间:2011-09-28

发表刊物:DALTON TRANSACTIONS

收录刊物:SCIE、EI、PubMed、Scopus

卷号:40

期号:36

页面范围:9085-9089

ISSN号:1477-9226

摘要:Room temperature near-IR phosphorescence of naphthalenediimide (NDI) was observed with N boolean AND N Pt(II) bisacetylide complex (Pt-NDI) in which the NDI was connected to Pt(II) center via acetylide. Pt-NDI shows intense absorption of visible light and long-lived NDI-localized excited state ((IL)-I-3) (tau(T) = 22.3 mu s). Pt-NDI was used as a triplet sensitizer for upconversion.