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论文类型：期刊论文

发表时间：2015-01-02

发表刊物：JOURNAL OF ORGANIC CHEMISTRY

收录刊物：SCIE、EI、Scopus

卷号：80

期号：1

页面范围：568-581

ISSN号：0022-3263

摘要：Rhodamine-bromonaphthaleneimide (RB-NI) and rhodamine-bromonaphthalenediimide (RB-NDI) dyads were prepared for switching of the triplet excited states. Bromo-NI or bromo-NDI parts in the dyads are the spin converters, i.e., the triplet state producing modules, whereas the RB unit is the acid-activatable electron donor/energy acceptor. NI and NDI absorb at 359 and 541 nm, and the T1 state energy levels are 2.25 and 1.64 eV, respectively. RB undertakes the reversible spirolactam (RB-c) <-> opened amide (RB-o) transformation. RB-c shows no visible light absorption, and the triplet-state energy level is E-T1 = 3.36 eV. Conversely RB-o shows strong absorption at 557 nm, and E-T1 is 1.73 eV. Thus, the acid-activated fluorescence-resonance-energy-transfer (FRET) competes with the ISC of NI or NDI. No triplet state was observed for the dyads with nanosecond time-resolved transient absorption spectroscopy. Upon addition of acid, strong fluorescence and long-living triplet excited states were observed. Thus, the producing of triplet state is acid-activatable. The triplet state of RB-NI is localized on RB-o part, whereas in RB-NDI the triplet state is delocalized on both the NDI and RB-o units. The ISC of spin converter was not outcompeted by RET. These studies are useful for switching of triplet excited state.