Release Time:2019-03-13  Hits:

Indexed by: Journal Article

Date of Publication: 2016-01-07

Journal: PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Included Journals: Scopus、PubMed、SCIE

Volume: 18

Issue: 1

Page Number: 190-196

ISSN: 1463-9076

Abstract: Titanium silicalite (TS-1) zeolites with different titanium species were synthesized and characterized by ultraviolet (UV)-Raman, ultraviolet visible (UV-Vis) diffuse reflectance spectroscopies and by the NH3 temperature programmed desorption (NH3-TPD) method. The roles of different titanium species in TS-1 samples have been investigated by gas chromatography-Raman spectrometry (GC-Raman) during the propylene epoxidation process. For the first time, a positive correlation was found among the concentration of framework Ti species, the amount of active intermediate Ti-OOH (eta(2)) and the conversion of propylene by the in situ GC-Raman technique. The results give evidence that the framework titanium species is the active center and Ti-OOH (eta(2)) is the active intermediate. The presence of extra framework Ti species is harmful to propylene epoxidation. Furthermore, the amorphous Ti species has a more negative effect on the yield of propylene oxide (PO) than the anatase TiO2. The NH3-TPD results reveal that the amorphous Ti species are more acidic and thus should be mainly responsible for the further conversion of PO.