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Indexed by:期刊论文

Date of Publication:2012-04-01

Journal:JOURNAL OF CATALYSIS

Included Journals:SCIE、EI

Volume:288

Page Number:1-7

ISSN No.:0021-9517

Key Words:TS-1; Amorphous Ti species; UV Raman spectroscopy; Resonance enhancement; Hammett indicator titration; Sulfosalt inactivation

Abstract:The nature of the amorphous Ti species in titanium silicalite-1 (TS-1) was investigated by UV Raman spectroscopy (UV Raman), UV-vis diffuse reflectance spectroscopy (UVDRS), infrared spectroscopy (IR), and Hammett indicator titration methods. A new Raman feature at 700 cm(-1), which is closely related to the UVDRS band at 260-280 nm, is first assigned to a totally symmetric vibration of hexacoordinated Ti-O-Ti linkages of the amorphous Ti species. The amorphous Ti species in TS-1 can be formed easily under the synthesis conditions in the presence of Na+ or after treatment in ammonia solution. The results reveal that the amorphous Ti species is the main factor in the enhanced acidity and H2O2 decomposition ability of TS-1. A sulfosalt impregnation method has been proved effective in reducing the adverse effect of the amorphous Ti species. (C) 2011 Elsevier Inc. All rights reserved.