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论文类型：期刊论文

发表时间：2012-02-01

发表刊物：CHEMCATCHEM

收录刊物：SCIE、EI、Scopus

卷号：4

期号：2

页面范围：260-264

ISSN号：1867-3880

关键字：dehydrogenation; molybdenum; nanotubes; phosphorus; supported catalysts

摘要：Catalytic performance of MoOxPOx supported on oxidized carbon nanotube (oCNT) catalysts for oxidative dehydrogenation of propane has been investigated. The catalysts were characterized by XRD, TEM, and IR spectroscopy techniques and then tested through the propane oxidation dehydrogenation reaction. The results reveal that the addition of MoOx significantly improves the catalytic activity but reduces the selectivity to propene. In contrast, adding POx decreases the reactivity and increases the selectivity by suppressing the combustion reaction. Adding both POx and MoOx can improve the selectivity at the same conversion rate and thus increase the yield of the catalyst. As compared to MoOx/oCNTs, the stability of the MoOxPOx/oCNT catalyst is significantly improved. This is because the addition of POx can promote MoOx dispersion on the CNT surface and hence improve the catalytic performance.