大连理工大学主页平台管理系统 Changhai Liang--Home-- A novel approach to synthesize highly selective nickel silicide catalysts for phenylacetylene semihydrogenation

Paper Publications

A novel approach to synthesize highly selective nickel silicide catalysts for phenylacetylene semihydrogenation

Hits:
Indexed by:
会议论文
First Author:
Chen, Xiao
Co-author:
Zhao, Anqi,Shao, Zhengfeng,Ma, Zhiqiang,Liang, Changhai
Date of Publication:
2010-07-11
Included Journals:
EI、CPCI-S、SCIE
Document Type:
A
Volume:
175
Page Number:
77-84
Key Words:
nickel silicide; carbon template; silicidization; phenylacetylene semihydrogenation
Abstract:
Nickel silicides (NiSi(x)) have been prepared by carbon template for nanostructured NiO and further silicidization with SiH(4)/H(2) at relatively low temperature and atmospheric pressure. The results showed that the formation of nickel silicides involves the following sequence, Ni (cubic) -> Ni(2)Si (orthorhombic) -> NiSi (orthorhombic) -> NiSi(2) (cubic), with increasing temperatures. The as-prepared nickel silicides showed above 92% selectivity to styrene in the semihydrogenation of phenylacetylene due to the electronic and geometrical effects derived from the addition of Si into Ni particles.

Pre One:Microwave-assisted preparation of Mo(2)C/CNTs nanocomposites as an efficient support for electrocatalysts toward oxygen reduction reaction

Next One:Naphthalene Hydrogenation over Silica Supported Nickel Phosphide in the Absence and Presence of N-Containing Compounds