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Synthesis of Subnanometer-Sized Gold Clusters by a Simple Milling-Mediated Solid Reduction Method

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Indexed by:期刊论文

Date of Publication:2018-04-01

Journal:CHINESE JOURNAL OF CHEMISTRY

Included Journals:SCIE、Scopus

Volume:36

Issue:4

Page Number:329-332

ISSN No.:1001-604X

Key Words:solid reduction; subnanometer-sized clusters; gold catalysts; CO2 hydrogenation

Abstract:An effective solvent-free method based on a solid-reduction process was developed to fabricate ultrafine gold catalysts. By this method we revealed a strong size-dependent activity of Au species in which subnanometer-sized clusters exhibited the best activity in the hydrogenation of CO2 to formate, with a turnover number of up to 9278 over 7 h at 90 degrees C.

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