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论文类型：期刊论文

发表时间：2014-12-01

发表刊物：CHEMSUSCHEM

收录刊物：SCIE、EI、PubMed、Scopus

卷号：7

期号：12

页面范围：3476-3482

ISSN号：1864-5631

关键字：active sites; carbon nanotubes; dehydrogenation; hydrocarbons; phosphorous

摘要：Ketonic/quinonic C=O groups on the surface of a carbon matrix are capable of abstracting hydrogen in C-H bonds from hydrocarbons and enable them to selectively convert into corresponding unsaturated hydrocarbons; this process is the oxidative dehydrogenation (ODH) reaction. However, a variety of inevitable defects or graphene edges and other oxygen-containing groups on the carbon matrix are detrimental to the selective production of alkenes due to their high activity towards overoxidation. Herein, we show that phosphate can not only impede the total oxidation but also cover the selective C=O groups, hence allowing its use as a modulator to defects and oxygen-containing functional groups on the multiwalled carbon nanotubes, regulating the distribution of active sites and related catalytic targets.