梁长海

个人信息Personal Information

教授

博士生导师

硕士生导师

任职 : 大连理工大学成都研究院院长

性别:男

毕业院校:中科院大连化学物理研究所

学位:博士

所在单位:化工学院

学科:化学工艺. 物理化学. 功能材料化学与化工

办公地点:大连理工大学西部校区化工综合楼A401室

联系方式:辽宁省大连市高新区凌工路2号,邮编116024

电子邮箱:changhai@dlut.edu.cn

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Preparation and Formation Mechanism of Highly Dispersed Manganese Silicide on Silica by MOCVD of Mn(CO)(5)SiCl3

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论文类型:期刊论文

发表时间:2013-03-01

发表刊物:CHEMICAL VAPOR DEPOSITION

收录刊物:SCIE、EI、Scopus

卷号:19

期号:1-3

页面范围:68-73

ISSN号:0948-1907

关键字:Formation mechanism; In-situ FTIR; Manganese silicide; Mn(CO)(5)SiCl3; MOCVD

摘要:MnSi nanoparticles on silica are prepared by metal-organic (MO)CVD of Mn(CO)5SiCl3 as a single-source precursor. Mn(CO)5SiCl3 is synthesized from Mn2(CO)10 and SiHCl3 using standard Schlenk techniques, and confirmed by Fourier transform infrared (FTIR), single-crystal X-ray diffraction (XRD), and 13C and 29Si nuclear magnetic resonance (NMR). Powder XRD patterns, high resolution transmission electron microscopy (HRTEM), elemental maps, and energy dispersive X-ray (EDX) spectroscopy show that MnSi particles, with a size of about 56nm, are uniformly dispersed on the silica support. The formation mechanism of MnSi nanoparticles on silica is investigated by in-situ FTIR spectroscopy. The results demonstrate the formation details of MnSi nanoparticles from Mn(CO)5SiCl3 through the elimination of carbonyl groups and dissociation of SiCl bonds with the promotion of H2.