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Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production

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Indexed by:期刊论文

Date of Publication:2017-01-01

Journal:RSC ADVANCES

Included Journals:SCIE、EI

Volume:7

Issue:77

Page Number:48989-48993

ISSN No.:2046-2069

Abstract:A positively charged redox-active metal-organic triangle containing three redox-active copper centres was developed to encapsulate anionic organic dyes (fluorescein) through a weak host-guest interaction for photocatalytic hydrogen production. The unique geometry enforces a distorted square planar coordination suitable for proton reduction. Control experiments with a mononuclear copper complex as a reference photocatalyst and inactive ATP as an inhibitor were performed to confirm this enzymatic photocatalytic behaviour.

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