Release Time:2019-03-13  Hits:

Indexed by: Journal Article

Date of Publication: 2019-01-01

Journal: ACS CATALYSIS

Included Journals: Scopus、SCIE

Volume: 9

Issue: 1

Page Number: 422-430

ISSN: 2155-5435

Key Words: two-photon photocatalysis; metal-organic framework; visible light; coupling reactions; nonlinear optics

Abstract: A multiple-photon photochemical process breaks the existing energy limitation of visible-light photo catalysis. Through careful incorporation of both bis(3,5-dicarboxyphenyl)pyridine and bis (3,5-dicarboxyphenyl)-methylpyridinium ligands into a single metal-organic framework (MOF), we report herein photocatalytic C-N and C-C oxidative coupling reactions that evidenced the direct two photon response process. Time-dependent luminescence decay studies demonstrated that the framework reached the same excited state by a two-photon absorption process as that reached via a single-photon absorption process, and the excited state could activate substrates even under NIR-light irradiation. Under 660 nm light-emitting diode (LED) irradiation, both the photooxidative C-N coupling reaction of benzylamine to form benzylidene-1-phenylmethanamine and the C-C coupling reaction between nitromethane and N-phenyltetrahydroisoquinoline were accelerated directly in a heterogeneous manner. Control experiments suggested that minimal byproducts were formed under the NIR-light irradiation compared to those of the UV light catalytic reactions. Importantly, photon intensity-dependent studies exhibited a nonlinear correlation between catalytic efficiency of multivariate MOFs (MTV-MOFs) and photon power intensity, verifying the two photon responsive nature, which indicated that metal-organic framework with high density and ordered photoactive motifs could enhance the two-photon absorption ability, thereby improving photocatalytic efficiency even under LED irradiation.