Release Time:2019-03-13  Hits:

Indexed by: Journal Article

Date of Publication: 2016-01-01

Journal: RSC ADVANCES

Included Journals: EI、SCIE

Volume: 6

Issue: 57

Page Number: 51936-51940

ISSN: 2046-2069

Abstract: A 3D breathing MOF was synthesized by hierarchical methods for light-driven acceleration of the site-selective C(sp(3))-H activation. The 1D channels of the assembled MOF can encapsulate the reaction substrates via a breathing process that was observed by single-crystal X-ray analyses. The weak interactions between the encapsulated substrate and the photoactive center facilitated the in situ generation of the active alkyl radicals.