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Indexed by:期刊论文

Date of Publication:2016-01-01

Journal:RSC ADVANCES

Included Journals:SCIE、EI

Volume:6

Issue:57

Page Number:51936-51940

ISSN No.:2046-2069

Abstract:A 3D breathing MOF was synthesized by hierarchical methods for light-driven acceleration of the site-selective C(sp(3))-H activation. The 1D channels of the assembled MOF can encapsulate the reaction substrates via a breathing process that was observed by single-crystal X-ray analyses. The weak interactions between the encapsulated substrate and the photoactive center facilitated the in situ generation of the active alkyl radicals.