A photosensitizing decatungstate-based MOF as heterogeneous photocatalyst for the selective C-H alkylation of aliphatic nitriles
Release Time:2019-03-09 Hits:
Indexed by: Journal Papers
Date of Publication: 2016-03-28
Journal: CHEMICAL COMMUNICATIONS
Included Journals: PubMed、SCIE
Volume: 52
Issue: 25
Page Number: 4714-4717
ISSN: 1359-7345
Abstract: The efficient photosensitizing of decatungstate-based MOF with 1D channels was achieved via in situ synthesis under solvothermal conditions for light driven acceleration of beta- or gamma-site C-H alkylation of aliphatic nitriles. The high catalytic efficiency, excellent size selectivity, high stability and good recyclability of the photocatalyst offer an environmentally-friendly route for widening the scope of accessible nitriles in both laboratory and industry.
Prev One:Organized Aggregation Makes Insoluble Perylene Diimide Efficient for the Reduction of Aryl Halides via Consecutive Visible Light-Induced Electron-Transfer Processes
Next One:A new copper(II) selective fluorescence probe based on naphthalimide: Synthesis, mechanism and application in living cells