Hits:

Indexed by:期刊论文

Date of Publication:2014-02-01

Journal:DYES AND PIGMENTS

Included Journals:SCIE、EI、Scopus

Volume:101

Page Number:254-260

ISSN No.:0143-7208

Key Words:Chemosensor; Nucleoside; Colorimetric and fluorescent; Naphthyridine; Rhodamine B; Cell imaging

Abstract:A novelty rhodamine B based chemosensor containing 2-amino-7-methyl-1,8-naphthyridine moiety was designed and synthesized for colorimetric and fluorescent response on corresponding nucleoside polyphosphates through multi-hydrogen bond interaction in aqueous solution. The supramolecular recognition between the RBS and Cytidine-5'-diphosphate disodium hydrate (CDP) was investigated carefully: H-1 nuclear magnetic resonance confirmed that the formation of multi-hydrogen bonds between naphthyridine moiety and the nucleoside base group could untie the spiro structure of RBS, and the ESI-MS spectra proved the formation of the 1:1 complexation species between RBS and CDP. The strong emission response of the RBS toward COP and Adenosine-5'-triphosphate disodium trihydrate (ATP) ensures its application in living cells imaging. (C) 2013 Elsevier Ltd. All rights reserved.