Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-10-01

Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals: Scopus、PubMed、EI、SCIE

Volume: 51

Issue: 40

Page Number: 10127-10131

ISSN: 1433-7851

Key Words: 1; 3-dipolar cycloaddition; asymmetry catalysis; homochiral crystallization; metal-organic framework; silver

Abstract: Enantiomeric silver-based MOFs were obtained through a homochiral crystallization of cinchonine and cinchonidine enantiomers as chiral adducts with silver. These MOFs exhibited excellent catalytic activity for asymmetric [3+2] cycloaddition (see scheme), giving products with high enantioselectivity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.