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Indexed by:期刊论文

Date of Publication:2012-10-01

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:SCIE、EI、PubMed、Scopus

Volume:51

Issue:40

Page Number:10127-10131

ISSN No.:1433-7851

Key Words:1; 3-dipolar cycloaddition; asymmetry catalysis; homochiral crystallization; metal-organic framework; silver

Abstract:Enantiomeric silver-based MOFs were obtained through a homochiral crystallization of cinchonine and cinchonidine enantiomers as chiral adducts with silver. These MOFs exhibited excellent catalytic activity for asymmetric [3+2] cycloaddition (see scheme), giving products with high enantioselectivity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.