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Indexed by:期刊论文

Date of Publication:2012-04-27

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:PubMed、SCIE、EI、Scopus

Volume:51

Issue:18

Page Number:4367-4370

ISSN No.:1433-7851

Key Words:charge transfer; electron transfer; magnetic properties; spin crossover; transition metals

Abstract:A light change: A linear cyanido-bridged Fe2Co compound (see picture) exhibits a reversible, thermally induced cooperative charge transfer transition accompanying spin transition and polar-nonpolar transformation in the trinuclear cluster. The change in magnetic properties and polarity could also be induced by irradiation with light. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.