Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2010-10-20

Journal: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Included Journals: Scopus、ESI高被引论文、PubMed、EI、SCIE

Volume: 132

Issue: 41

Page Number: 14321-14323

ISSN: 0002-7863

Abstract: Homochiral crystallizations of two enantiomeric metal-organic frameworks (MOFs) Ce-MDIP1 and Ce-MDIP2 were achieved by using L- or D-BCIP as chiral inductions, respectively, where the chiralities were characterized by solid state CD spectra. Ce-MDIPs exhibit excellent catalytic activity and high enantioselectivity for the asymmetric cyanosilylation of aromatic aldehydes; the homochiral Cd-TBT MOF having L-PYI as a chiral adduct exhibits stereochemical catalysis toward the Aldol reactions.