Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production
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论文类型：期刊论文
发表时间：2017-01-01
发表刊物：RSC ADVANCES
收录刊物：EI、SCIE
卷号：7
期号：77
页面范围：48989-48993
ISSN号：2046-2069
摘要：A positively charged redox-active metal-organic triangle containing three redox-active copper centres was developed to encapsulate anionic organic dyes (fluorescein) through a weak host-guest interaction for photocatalytic hydrogen production. The unique geometry enforces a distorted square planar coordination suitable for proton reduction. Control experiments with a mononuclear copper complex as a reference photocatalyst and inactive ATP as an inhibitor were performed to confirm this enzymatic photocatalytic behaviour.