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论文类型：期刊论文

发表时间：2016-01-01

发表刊物：RSC ADVANCES

收录刊物：EI、SCIE

卷号：6

期号：57

页面范围：51936-51940

ISSN号：2046-2069

摘要：A 3D breathing MOF was synthesized by hierarchical methods for light-driven acceleration of the site-selective C(sp(3))-H activation. The 1D channels of the assembled MOF can encapsulate the reaction substrates via a breathing process that was observed by single-crystal X-ray analyses. The weak interactions between the encapsulated substrate and the photoactive center facilitated the in situ generation of the active alkyl radicals.