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论文类型：期刊论文

发表时间：2015-01-14

发表刊物：DALTON TRANSACTIONS

收录刊物：PubMed、SCIE、Scopus

卷号：44

期号：2

页面范围：464-467

ISSN号：1477-9226

摘要：It is a challenge to synthesize a porous tubular coordination polymer with magnetic properties. Utilizing [Fe-II(bipy)(CN)(4)](2-) (bipy = 2,2'-bipyridine) as the building block to react with Mn2+, we successfully synthesized a cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions. The inner surface of the heterometallic tube is hydrophilic, whereas the outer surface is hydrophobic. The framework is stable up to 320 degrees C and can adsorb N-2 and CO2. The ferromagnetic interactions were transmitted via the diamagnetic N-C-Fe-II-C-N species between Mn2+ ions in the tube.