Proline adducts of metallo-organic, sextuply-stranded lanterns as homogeneous catalysts for asymmetric catalysis
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论文类型：期刊论文
发表时间：2013-12-02
发表刊物：TETRAHEDRON
收录刊物：Scopus、SCIE
卷号：69
期号：48
页面范围：10477-10481
ISSN号：0040-4020
关键字：Metallo-organic polyhedron; Chirality; Proline; Asymmetric catalysis; Cyanosilylation
摘要：Two homochiral metal-organic, sextuply-stranded, lantern-like complexes, Ce-L-Pro1 and Ce-D-Pro1, were synthesized via self-assembly by incorporating a L or D-pyrrolidine moiety within the respective ligands. The Ce-Pro1 complexes are comprised of chiral pyrrolidine-containing ligands and have lantern-like cavities. They function as asymmetric catalysts that promote cyanosilylation reactions with good conversions and enantioselectivity. (C) 2013 Published by Elsevier Ltd.