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论文类型：期刊论文

发表时间：2013-12-02

发表刊物：TETRAHEDRON

收录刊物：SCIE、Scopus

卷号：69

期号：48

页面范围：10477-10481

ISSN号：0040-4020

关键字：Metallo-organic polyhedron; Chirality; Proline; Asymmetric catalysis; Cyanosilylation

摘要：Two homochiral metal-organic, sextuply-stranded, lantern-like complexes, Ce-L-Pro1 and Ce-D-Pro1, were synthesized via self-assembly by incorporating a L or D-pyrrolidine moiety within the respective ligands. The Ce-Pro1 complexes are comprised of chiral pyrrolidine-containing ligands and have lantern-like cavities. They function as asymmetric catalysts that promote cyanosilylation reactions with good conversions and enantioselectivity. (C) 2013 Published by Elsevier Ltd.