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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：南京大学
学位：博士
所在单位：化工学院
电子邮箱：hecheng@dlut.edu.cn
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Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain
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论文类型：期刊论文
发表时间：2012-05-21
发表刊物：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
收录刊物：SCIE、EI、PubMed、Scopus
卷号：51
期号：21
页面范围：5119-5123
ISSN号：1433-7851
关键字：chain structures; charge transfer; cobalt; iron; magnetic properties
摘要：Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated FeIII2CoII chains of {[Fe(pzTp)(CN)3]2Co(4-styrylpyridine)2} 2H 2O 2CH3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.