Reversible Electron Transfer in a Linear {Fe2Co} Trinuclear Complex Induced by Thermal Treatment and Photoirraditaion
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论文类型：期刊论文
发表时间：2012-04-27
发表刊物：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
收录刊物：Scopus、EI、SCIE、PubMed
卷号：51
期号：18
页面范围：4367-4370
ISSN号：1433-7851
关键字：charge transfer; electron transfer; magnetic properties; spin crossover; transition metals
摘要：A light change: A linear cyanido-bridged Fe2Co compound (see picture) exhibits a reversible, thermally induced cooperative charge transfer transition accompanying spin transition and polar-nonpolar transformation in the trinuclear cluster. The change in magnetic properties and polarity could also be induced by irradiation with light. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.