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论文类型：期刊论文

发表时间：2012-03-14

发表刊物：DALTON TRANSACTIONS

收录刊物：SCIE、EI、PubMed、Scopus

卷号：41

期号：10

页面范围：3072-3077

ISSN号：1477-9226

摘要：Two enantiomeric Zn-MOFs, having L- or D-proline chiral functionality, were achieved through in situ click reactions by modifying two opposite chiral adducts within the same pre-assembled achiral MOFs, respectively. Both of them exhibited remarkable catalytic activities in the relative asymmetric aldol reactions, and led to the formation of opposite enantiomorphs. The significant advantage of this approach not only includes the conversion of chemically and thermally robust MOFs into enantiomeric chiral material having catalytically active sites, but also involves the potential applications in asymmetric transformations with desirable chiralities of a special enantiomorph.