何成

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教授

博士生导师

硕士生导师

性别:男

毕业院校:南京大学

学位:博士

所在单位:化工学院

电子邮箱:hecheng@dlut.edu.cn

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An L-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions

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论文类型:期刊论文

发表时间:2011-08-07

发表刊物:CHEMICAL COMMUNICATIONS

收录刊物:SCIE、PubMed、Scopus

卷号:47

期号:29

页面范围:8415-8417

ISSN号:1359-7345

摘要:A homochiral metal-organic triangle Co-Pro1 was achieved via self-assembly by incorporating a L-proline moiety within the corresponding ligand. Co-Pro1 comprised L-proline moieties as asymmetric catalytic active sites and a helical-like cavity, it worked as an asymmetric catalyst to prompt aldol reactions with size-, stereo-and enantioselectivity.