An L-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions
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论文类型：期刊论文
发表时间：2011-08-07
发表刊物：CHEMICAL COMMUNICATIONS
收录刊物：Scopus、PubMed、SCIE
卷号：47
期号：29
页面范围：8415-8417
ISSN号：1359-7345
摘要：A homochiral metal-organic triangle Co-Pro1 was achieved via self-assembly by incorporating a L-proline moiety within the corresponding ligand. Co-Pro1 comprised L-proline moieties as asymmetric catalytic active sites and a helical-like cavity, it worked as an asymmetric catalyst to prompt aldol reactions with size-, stereo-and enantioselectivity.