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论文类型：期刊论文

发表时间：2010-10-20

发表刊物：JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

收录刊物：Scopus、ESI高被引论文、PubMed、EI、SCIE

卷号：132

期号：41

页面范围：14321-14323

ISSN号：0002-7863

摘要：Homochiral crystallizations of two enantiomeric metal-organic frameworks (MOFs) Ce-MDIP1 and Ce-MDIP2 were achieved by using L- or D-BCIP as chiral inductions, respectively, where the chiralities were characterized by solid state CD spectra. Ce-MDIPs exhibit excellent catalytic activity and high enantioselectivity for the asymmetric cyanosilylation of aromatic aldehydes; the homochiral Cd-TBT MOF having L-PYI as a chiral adduct exhibits stereochemical catalysis toward the Aldol reactions.