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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：南京大学
学位：博士
所在单位：化工学院
电子邮箱：hecheng@dlut.edu.cn
Association of ruthenium complexes [Ru(bpy)(3)](2+) or [Ru(bpy)(2)(Mebpy-py)](2+) with Dawson polyanions alpha-[P2W18O62](6-) or alpha(2)-[Fe-III(H2O)P2W17O61](7-)
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论文类型：期刊论文
发表时间：2008-11-01
发表刊物：CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
收录刊物：SCIE、EI、Scopus
卷号：86
期号：11
页面范围：1034-1043
ISSN号：0008-4042
关键字：electrochemistry; polyoxometalate; ruthenium complex; electrostatic complex
摘要：The formation of electrostatically linked complexes between [Ru(bpy)(3)]Cl-2 or [Ru(bpy)(2)(Mebpy-py)](PF6)(2) and (TBA)(6)alpha-[P2W18O62] or (TBA)(5)K-2 alpha(2)-[Fe-III(H2O) P2W17O61] in solution were studied by steady-state absorption and luminescence spectroscopy. The stoichiometry and global association constants of the formed complexes were obtained by the Job method. The formed complexes were characterized by H-1 and P-31 NMR spectroscopy and their ical properties compared to the precursor compounds were investigated by using the cyclic voltammetry method.