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论文类型：期刊论文

发表时间：2014-02-27

发表刊物：JOURNAL OF PHYSICAL CHEMISTRY B

收录刊物：SCIE、EI、PubMed、Scopus

卷号：118

期号：8

页面范围：2226-2237

ISSN号：1520-6106

摘要：Without melting flow, linear ultrahigh molecular weight polyethylene (UHMWPE) provided X-ray intensity curve from only amorphous halo at 129.0 degrees C (surface temperature, T-s arisen by Joule heat) lower than the conventionally known melting point 145.5 degrees C on applying electric field to UHMWPE-nickel-coated carbon fiber (NiCF) composite. Such surprising phenomenon was analyzed by simultaneous measurements of X-ray intensity, electric current, and T-s as a function of time. The calculated radial distribution function revealed the amorphous structure with disordered chain arrangement. The appearance of such amorphous phase was arisen by the phenomenon that the transferring electrons between overlapped adjacent NiCFs by tunneling effect struck together with X-ray photons and some of the transferring electron flown out from the gap to UHMWPE matrix collided against carbon atoms of UHMWPE. The impact by the collision caused disordering chain arrangement in crystal grains.