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Redox-induced Ru(bpy)(3)(2+) -methylviologen radical formation and its dimerization in cucurbit[8]uril

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Indexed by:期刊论文

Date of Publication:2011-01-14

Journal:PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Included Journals:PubMed、SCIE、Scopus

Volume:13

Issue:2

Page Number:570-575

ISSN No.:1463-9076

Abstract:A redox-induced radical Ru(bpy)(3)(2+)-(CH2)(n)-MV+center dot (n = 4, 7) and its dimerization in cucurbit[8] uril (CB[8]) have been observed concomitantly in aqueous solution, which depends heavily on the length of the carbon chain linkage, in the case of n = 4, the characteristic pattern for the radical dimer is predominating, while that for the radical becomes dominated for n = 7.

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