Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2009-12-21

Journal: PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Included Journals: Scopus、PubMed、SCIE

Volume: 11

Issue: 47

Page Number: 11134-11139

ISSN: 1463-9076

Abstract: N-(4-Hydroxy-phenoxyethyl)-N'-ethyl-4,4'-bipyridium (1) can form a stable 1 : 1 inclusion complex with CB[8] in aqueous solution, in which the hydroxyphenol (HP) moiety is back-folded and inserted together with the viologen moiety into the cavity of CB[8]. When the ethyl viologen dication (EV2+) in 1 is reduced, chemically or electrochemically, an intramolecular partner radical (EV+center dot-HP)/CB[8] can be detected, meanwhile, a dynamic balance between the partner radical and the intermolecular radical dimer (EV+center dot-HP)(2)/CB[8] can be observed.