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Synthesis of a water-soluble macromolecular light stabilizer containing hindered amine structures

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Indexed by:期刊论文

Date of Publication:2013-02-01

Journal:CHINESE CHEMICAL LETTERS

Included Journals:SCIE、ISTIC、CSCD

Volume:24

Issue:2

Page Number:153-155

ISSN No.:1001-8417

Key Words:Water-soluble macromolecular light stabilizer; Hindered amine; Lightfastness of reactive dyes; Finishing

Abstract:A novel water-soluble macromolecular light stabilizer was synthesized by grafting 2-chloro-4,6-bis-[(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazine onto polyvinylamine. The intermediate 2-chloro-4,6-bis-[(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazine and the obtained macromolecular light stabilizer were characterized by H-1 NMR, HRMS, IR and UV spectroscopy. Cotton fabrics dyed with C.I. Reactive Yellow 145, C.I. Reactive Red 195 and C.I. Reactive Blue 19 were finished with the macromolecular light stabilizer, and the lightfastness of the dyes was tested. The results showed that the lightfastness of the reactive dyes was improved by 0.5-1.0 grade after being finished and the macromolecular light stabilizer exhibited good wash fastness and thermal stability. (C) 2013 Wei Ma. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

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