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Structure, Morphology, and Electromagnetic Properties of Manganese Dioxide with Ni Doping

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-09-01

Journal: JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM

Included Journals: Scopus、EI、SCIE

Volume: 27

Issue: 9

Page Number: 2139-2146

ISSN: 1557-1939

Key Words: Manganese dioxide; Ni doping; Structure; Morphology; Electromagnetic properties

Abstract: Hydrothermal synthesis between (NH (4))(2)S O-2 (8) and MnSO (4) was carried out to investigate the structure, morphology, and electromagnetic properties of Ni-doped MnO (2) with different doping amounts. The samples were characterized by X-ray powder diffraction (XRD), X-ray fluorescence spectrometry (XRF), scanning electron microscopy (SEM), and vector network analysis. The analysis results revealed that all the final products were alpha-MnO (2) and few amounts of gamma-MnO (2), and the morphology changed obviously with the increase of the Ni doping amount. The doping of Ni had a certain effect on the electromagnetic properties, and some other properties derived from electromagnetic performances were also investigated, such as dielectric and magnetic loss tangent and microwave-absorbing properties. All the reflection loss (RL) peaks of the final products were moving toward lower frequency with increasing thickness, and with the thickness of 2 mm, the final products all had the maximum effective absorption bandwidth (RL < -10 dB), and the Ni-doped MnO (2) had better reflection loss performance than the undoped MnO (2) in the range of high frequency.

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