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Indexed by:期刊论文

Date of Publication:2012-01-25

Journal:INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Included Journals:SCIE、EI、Scopus

Volume:51

Issue:3

Page Number:1158-1165

ISSN No.:0888-5885

Abstract:The reaction kinetics of the Fe(H)-induced catalytic oxidation of S(IV) in a concentration range of 10(-6) M <= [Fe(II)] <= 1 M was studied. The S(IV) catalytic oxidation reaction order for O-2 and HSO3- was found to be 0 and 1 in this iron concentration range. The reaction order toward Fe(II) was 1 for 10(-6) M <= [Fe(II)] <= 10(-4) M, 0 for 10(-4) M < [Fe(II)] <= 10(-2)M, and -0.2 for 10(-2) M <= [Fe(II)] <= 1 M. At 30-50 degrees C the activation energy values were low but increased after an increase in the ionic strength. The ionic strength had a negative influence on the reaction rate constant in the iron concentration range. By analyzing the radical mechanisms and reaction kinetic results, a simplified model for the Fe(II)-induced catalytic oxidation of S(IV), which enables a better analysis and elucidation of the experimental results, is proposed.