Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2015-01-14

Journal: DALTON TRANSACTIONS

Included Journals: Scopus、PubMed、SCIE

Volume: 44

Issue: 2

Page Number: 475-479

ISSN: 1477-9226

Abstract: Photocatalytic oxidation of organic compounds proceeded efficiently in a hybrid system with ruthenium aqua complexes as catalysts, BiVO4 as a light absorber, [Co(NH3)(5)Cl](2+) as a sacrificial electron acceptor and water as an oxygen source. The photogenerated holes in the semiconductor are used to oxidize molecular catalysts into the high-valent Ru-IV=O intermediates for 2e(-) oxidation.