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Indexed by:期刊论文

Date of Publication:2013-03-18

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:SCIE、EI、PubMed、Scopus

Volume:52

Issue:12

Page Number:3398-3401

ISSN No.:1433-7851

Key Words:artificial photosynthesis; binuclear catalyst; homogeneous catalysis; solar fuels; water splitting

Abstract:Solar fuels: Dinuclear ruthenium catalysts prepared from two covalently bridged monomeric catalytic units show outstanding activities towards the oxidation of water with high turnover numbers up to 43 000 and turnover frequencies up to 40 s-1 (see picture). Direct comparison of the performance parameters indicates that the dimers are significantly more active as catalysts than the monomers. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.