安海艳
Associate Professor Supervisor of Doctorate Candidates Supervisor of Master's Candidates
Gender:Female
Alma Mater:Northeast Normal University
Degree:Doctoral Degree
School/Department:College of Chemistry
Discipline:Inorganic Chemistry
Business Address:Chemical Complex Building C406
Contact Information:13664256422
E-Mail:anhy@dlut.edu.cn
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Indexed by:期刊论文
Date of Publication:2010-09-01
Journal:ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Included Journals:SCIE
Volume:636
Issue:11
Page Number:2016-2021
ISSN No.:0044-2313
Key Words:Polyoxometalates; Boron; Imidazole; Hybrid structure; Luminescence
Abstract:Two new hybrid compounds based on polyoxometaloborates, (HIm)(12)[MnBW(11)O(39)H](2)center dot 13H(2)O (1) and (HIm)(Im)[(Im)(4)Zn](2)[BW(12)O(40)]center dot 2H(2)O (2) (Im = imidazole), have been synthesized and characterized by elemental analyses, IR, UV, TG, and single-crystal X-ray diffraction. Compound 1 is made up of [MnBW(11)O(39)H](6)-polyoxoanions, which are coordinatively linked together by terminal oxygen atoms to yield an unprecedented one-dimensional chain that represents the first example of one-dimensional assemblies based on polyoxotungstoborates and transition metal cations. Adjacent inorganic chains are further in close contact by imidazole molecules to form a three-dimensional supramolecular channel framework by strong hydrogen-bonding interactions. Compound 2 exhibits a three-dimensional supramolecular architecture constructed from Keggin-type polyoxoanions [BW(12)O(40)](5) and zinc-imidazole coordination units by strong hydrogen-bonding interactions. Furthermore, both compounds exhibit interesting photoluminescence properties at room temperature.
Pre One:Three-Dimensional Architectures Based on Lanthanide-Substituted Double-Keggin-Type Polyoxometalates and Lanthanide Cations or Lanthanide-Organic Complexes
Next One:Chromium(III) Complexes with Chelating Anilido-Imine Ligands: Synthesis, Structures, and Catalytic Properties for Ethylene Polymerization
In 2002, Prof. Haiyan An received the B.S. degree in chemistry Northeast Normal University, Changchun, China; the M.S. in 2004 and the Ph.D. degree in 2007 in Key Laboratory of Polyoxometalates (POMs) Science of Ministry of Education. There were 30 papers published in Angew. Chem. Int. Ed., Inorg. Chem., Cryst. Growth Des., etc. during the degree. In 2006, she was awarded the Excellent Doctoral Dissertations Fund of Northeast Normal University. In July 2007, Prof. An joined College of Chemistry, Dalian University of Technology in the field of POMs. Her research interests are mainly focuse on the design, synthesis and properties’research of POM-based functional complexes with catalytic and drug activity. She has Undertaked two National Natural Science Foundation of China, one Specialized Research Fund for the Doctoral Program of Higher Education, one Natural Science foundation of Liaoning Province and one Scientific Research Foundation for Doctor of Liaoning Province. There are more than 30 SCI papers have been officially published in foreign periodicals during the work period, more than 20 of which list her as the first author and corresponding author.
