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论文类型：期刊论文
发表时间：2010-01-01
发表刊物：JOURNAL OF COORDINATION CHEMISTRY
收录刊物：SCIE、Scopus
卷号：63
期号：17
页面范围：3028-3041
ISSN号：0095-8972
关键字：Dawson-type phosphomolybdate; Alkali-metal coordination complex; Lanthanide coordination complex; 1-D chain; Supramolecular channel
摘要：In this study, a series of compounds based on Dawson-type phosphomolybdates, H3(C6NO2H6)2[K(H2O)3(C6NO2H5)3][P2Mo18O62] 5.5H2O (1), (C6NO2H6)6[Ln(H2O)7(C6NO2H5)2]2[P2Mo18O62]2 center dot 13.5H2O (Ln = Ce (2), La (3)) have been synthesized and characterized by elemental analysis, IR and UV-Vis spectroscopy methods, TG analysis, and single-crystal X-ray diffraction. Compound 1 consists of [P2Mo18O62]6- building units joined by potassium-pyridine-3-carboxylic acid complexes, resulting in a wavelike polyoxometalate (POM) chain, which further interacts with each other via intermolecular interactions to form a 3-D supramolecular channel framework containing guest water molecules. Compounds 2 and 3 possess a 3-D supramolecular framework with 1-D tunnel constructed from [P2Mo18O62]6- and mononuclear lanthanide coordination complex fragments. To the best of our knowledge, 1 not only represents the first example of 1-D hybrid assembly based on Dawson-type phosphomolybdate, but also the first hybrid compound constructed from Dawson-type POMs and alkali-metal coordination complex fragments.