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Hydrothermal Synthesis of beta-NaYF4:Yb, Er Nanocrystals with Upconversion Fluorescence Using Tetraethylene Pentamine as Chelating Ligand

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Indexed by:期刊论文

Date of Publication:2012-01-01

Journal:JOURNAL OF NANOMATERIALS

Included Journals:SCIE、EI、Scopus

Volume:2012

ISSN No.:1687-4110

Abstract:Novel chelating ligands are very significant for preparing nanocrystals with different morphologies and applications. In this paper, we directly introduced amine groups onto UCNPs by choosing a new chelating ligand tetraethylene pentamine (TEPA) to synthesis NaYF4:Yb, Er through hydrothermal method. The influences of rare earth concentration, the ratio of RE/TEPA, solvent composition, and reaction time on the morphology and fluorescence intensity of the as-prepared NaYF4:Yb, Er samples were systematically investigated and discussed. Field emission scanning electron microscopy (FE-SEM), powder X-ray diffraction (XRD), and upconversion luminescence spectroscopy were used to characterize the product. It was found that rare earth concentration, ratio of RE/TEPA, solvent composition, and reaction time were all responsible for the luminescent intensity and morphology.

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