Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-09-01

Journal: ACS MACRO LETTERS

Included Journals: Scopus、SCIE

Volume: 3

Issue: 9

Page Number: 896-899

ISSN: 2161-1653

Abstract: Lewis pair cooperation provides a facile approach for polymerizing dissymmetric divinyl polar monomers such as 4-vinylbenzyl methacrylate in excellent regioselectivity and high reactivity at mild conditions, affording soluble polymers bearing pendant active vinyl groups with high molecular weight (up to 6.4 x 10(5) g/mol) and narrow polydispersity (PDI < 1.5). ESI-TOF MS study demonstrated that the polymerization process only concerned the methacrylic double bond and selectively remained the pendant allylic or styrene C=C bond.