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Probing Site Cooperativity of Frustrated Phosphine/Borane Lewis Pairs by a Polymerization Study

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-02-05

Journal: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Included Journals: Scopus、EI、SCIE

Volume: 136

Issue: 5

Page Number: 1774-1777

ISSN: 0002-7863

Abstract: The first highly active phosphine (P)/borane (B) Lewis pair polymerization is promoted unexpectedly by P B adducts. The P and B site cooperativity is essential for achieving effective polymerization, as shown by this study examining the reactivity of a library of P/B Lewis pairs toward polymerization of a renewable acrylic monomer.

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