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Probing Site Cooperativity of Frustrated Phosphine/Borane Lewis Pairs by a Polymerization Study

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Indexed by:期刊论文

Date of Publication:2014-02-05

Journal:JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Included Journals:SCIE、EI、Scopus

Volume:136

Issue:5

Page Number:1774-1777

ISSN No.:0002-7863

Abstract:The first highly active phosphine (P)/borane (B) Lewis pair polymerization is promoted unexpectedly by P B adducts. The P and B site cooperativity is essential for achieving effective polymerization, as shown by this study examining the reactivity of a library of P/B Lewis pairs toward polymerization of a renewable acrylic monomer.

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